Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic a,-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary… Mehr…
Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic a,-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She describes the unprecedented and powerful catalytic asymmetric hydro-peroxi-dation of a,-enones, a process which produces optically active five-membered cyclic peroxyhemiketals in a single operation. She also proves the versatility and synthetic value of the cyclic peroxyhemiketals by converting them into highly enantioenriched acyclic and cyclic aldol products. Currently, these cyclic aldol products are inaccessible by any other synthetic means. Furthermore, cyclic peroxyhemiketals are precursors to optically active 1,2-dioxolanes which are of biological relevance. This work is a breakthrough in the field of asymmetric epoxidation chemistry and outlines the most efficient method in the literature for generating highly enantioselective cyclic epoxyketones known to date.; PDF; Scientific, Technical and Medical > Chemistry > Organic chemistry, Springer Berlin Heidelberg<
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Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic a,-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary… Mehr…
Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic a,-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She describes the unprecedented and powerful catalytic asymmetric hydro-peroxi-dation of a,-enones, a process which produces optically active five-membered cyclic peroxyhemiketals in a single operation. She also proves the versatility and synthetic value of the cyclic peroxyhemiketals by converting them into highly enantioenriched acyclic and cyclic aldol products. Currently, these cyclic aldol products are inaccessible by any other synthetic means. Furthermore, cyclic peroxyhemiketals are precursors to optically active 1,2-dioxolanes which are of biological relevance. This work is a breakthrough in the field of asymmetric epoxidation chemistry and outlines the most efficient method in the literature for generating highly enantioselective cyclic epoxyketones known to date.; PDF; Scientific, Technical and Medical > Chemistry > Organic chemistry, Springer Berlin Heidelberg<
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No. 9783642281181. Versandkosten:Instock, Despatched same working day before 3pm, zzgl. Versandkosten. Details...
(*) Derzeit vergriffen bedeutet, dass dieser Titel momentan auf keiner der angeschlossenen Plattform verfügbar ist.
Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic a,-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary… Mehr…
Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic a,-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She describes the unprecedented and powerful catalytic asymmetric hydro-peroxi-dation of a,-enones, a process which produces optically active five-membered cyclic peroxyhemiketals in a single operation. She also proves the versatility and synthetic value of the cyclic peroxyhemiketals by converting them into highly enantioenriched acyclic and cyclic aldol products. Currently, these cyclic aldol products are inaccessible by any other synthetic means. Furthermore, cyclic peroxyhemiketals are precursors to optically active 1,2-dioxolanes which are of biological relevance. This work is a breakthrough in the field of asymmetric epoxidation chemistry and outlines the most efficient method in the literature for generating highly enantioselective cyclic epoxyketones known to date.; PDF; Scientific, Technical and Medical > Chemistry > Organic chemistry, Springer Berlin Heidelberg<
hive.co.uk
No. 9783642281181. Versandkosten:Instock, Despatched same working day before 3pm, zzgl. Versandkosten. Details...
(*) Derzeit vergriffen bedeutet, dass dieser Titel momentan auf keiner der angeschlossenen Plattform verfügbar ist.
In this book, Corinna Reisinger describes a new organocatalytic asymmetric epoxidation of cyclic and acyclic a,-unsaturated ketones, using primary amine salts as catalysts, and hydrogen p… Mehr…
In this book, Corinna Reisinger describes a new organocatalytic asymmetric epoxidation of cyclic and acyclic a,-unsaturated ketones, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant.; PDF; Scientific, Technical and Medical > Chemistry > Organic chemistry, Gabler Verlag<
hive.co.uk
No. 9783642281181. Versandkosten:Instock, Despatched same working day before 3pm, zzgl. Versandkosten. Details...
(*) Derzeit vergriffen bedeutet, dass dieser Titel momentan auf keiner der angeschlossenen Plattform verfügbar ist.
Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic a,-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary… Mehr…
Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic a,-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She describes the unprecedented and powerful catalytic asymmetric hydro-peroxi-dation of a,-enones, a process which produces optically active five-membered cyclic peroxyhemiketals in a single operation. She also proves the versatility and synthetic value of the cyclic peroxyhemiketals by converting them into highly enantioenriched acyclic and cyclic aldol products. Currently, these cyclic aldol products are inaccessible by any other synthetic means. Furthermore, cyclic peroxyhemiketals are precursors to optically active 1,2-dioxolanes which are of biological relevance. This work is a breakthrough in the field of asymmetric epoxidation chemistry and outlines the most efficient method in the literature for generating highly enantioselective cyclic epoxyketones known to date.; PDF; Scientific, Technical and Medical > Chemistry > Organic chemistry, Springer Berlin Heidelberg<
No. 9783642281181. Versandkosten:Instock, Despatched same working day before 3pm, zzgl. Versandkosten.
Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic a,-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary… Mehr…
Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic a,-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She describes the unprecedented and powerful catalytic asymmetric hydro-peroxi-dation of a,-enones, a process which produces optically active five-membered cyclic peroxyhemiketals in a single operation. She also proves the versatility and synthetic value of the cyclic peroxyhemiketals by converting them into highly enantioenriched acyclic and cyclic aldol products. Currently, these cyclic aldol products are inaccessible by any other synthetic means. Furthermore, cyclic peroxyhemiketals are precursors to optically active 1,2-dioxolanes which are of biological relevance. This work is a breakthrough in the field of asymmetric epoxidation chemistry and outlines the most efficient method in the literature for generating highly enantioselective cyclic epoxyketones known to date.; PDF; Scientific, Technical and Medical > Chemistry > Organic chemistry, Springer Berlin Heidelberg<
No. 9783642281181. Versandkosten:Instock, Despatched same working day before 3pm, zzgl. Versandkosten.
Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic a,-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary… Mehr…
Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic a,-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She describes the unprecedented and powerful catalytic asymmetric hydro-peroxi-dation of a,-enones, a process which produces optically active five-membered cyclic peroxyhemiketals in a single operation. She also proves the versatility and synthetic value of the cyclic peroxyhemiketals by converting them into highly enantioenriched acyclic and cyclic aldol products. Currently, these cyclic aldol products are inaccessible by any other synthetic means. Furthermore, cyclic peroxyhemiketals are precursors to optically active 1,2-dioxolanes which are of biological relevance. This work is a breakthrough in the field of asymmetric epoxidation chemistry and outlines the most efficient method in the literature for generating highly enantioselective cyclic epoxyketones known to date.; PDF; Scientific, Technical and Medical > Chemistry > Organic chemistry, Springer Berlin Heidelberg<
No. 9783642281181. Versandkosten:Instock, Despatched same working day before 3pm, zzgl. Versandkosten.
In this book, Corinna Reisinger describes a new organocatalytic asymmetric epoxidation of cyclic and acyclic a,-unsaturated ketones, using primary amine salts as catalysts, and hydrogen p… Mehr…
In this book, Corinna Reisinger describes a new organocatalytic asymmetric epoxidation of cyclic and acyclic a,-unsaturated ketones, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant.; PDF; Scientific, Technical and Medical > Chemistry > Organic chemistry, Gabler Verlag<
No. 9783642281181. Versandkosten:Instock, Despatched same working day before 3pm, zzgl. Versandkosten.
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Detailangaben zum Buch - Epoxidations and Hydroperoxidations of ?,?-Unsaturated Ketones
EAN (ISBN-13): 9783642281181 ISBN (ISBN-10): 3642281184 Erscheinungsjahr: 2012 Herausgeber: Springer Berlin 257 Seiten Sprache: eng/Englisch
Buch in der Datenbank seit 2012-11-29T10:14:17+01:00 (Berlin) Detailseite zuletzt geändert am 2024-02-06T19:17:21+01:00 (Berlin) ISBN/EAN: 9783642281181
ISBN - alternative Schreibweisen: 3-642-28118-4, 978-3-642-28118-1 Alternative Schreibweisen und verwandte Suchbegriffe: Autor des Buches: reisinger, reising, reis, corin, cori Titel des Buches: ket, asymmetric organocatalysis, keto, unsaturated
Daten vom Verlag:
Autor/in: Corinna Reisinger Titel: Springer Theses; Epoxidations and Hydroperoxidations of α,β-Unsaturated Ketones - An Approach through Asymmetric Organocatalysis Verlag: Springer; Springer Berlin 260 Seiten Erscheinungsjahr: 2012-06-01 Berlin; Heidelberg; DE Sprache: Englisch 96,29 € (DE) 99,00 € (AT) 118,00 CHF (CH) Available XVI, 260 p.
EA; E107; eBook; Nonbooks, PBS / Chemie/Organische Chemie; Organische Chemie; Verstehen; Asymmetric counteranion-directed catalysis; Asymmetric peroxidation reactions; Asymmetric synthesis of epoxy ketones; Cinchona alkaloid derivatives as organocatalysts; Organocatalytic epoxidation of unsaturated ketones; B; Organic Chemistry; Catalysis; Industrial Chemistry; Chemistry and Materials Science; Katalyse; Industrielle Chemie und Chemietechnologie; BB
Background.- Asymmetric Organocatalysis.- Catalytic Asymmetric Epoxidation of Electron-Deficient Olefins.- Synthesis and Relevance of 3-Hydroxy-1,2-dioxolanes and 1,2-Dioxolanes.- Objectives of this Ph.D. Work.- Results and Discussion.- Catalytic Asymmetric Epoxidation of Cyclic Enones.- Catalytic Asymmetric Epoxidation and Hydroperoxidation of Acyclic Enones.- Synthetic Transformations of Optically Active a,ß-Epoxy Ketones and 3-Hydroxy-1,2-dioxolanes.- Summary and Conclusions.- Mechanistic Considerations.- Preparation of Starting Materials.- Catalyst Synthesis.- Summary.- Outlook.- Experimental Part.- General Experimental Conditions.- Catalytic Asymmetric Epoxidation of Cyclic Enones.- Catalytic Asymmetric Hydroperoxidation and Epoxidation of Acyclic Enones.- Synthetic Transformations of Optically Active Products.- Preparation of Starting Materials.- Catalyst Synthesis. Nominated by the Max-Planck-Institut für Kohlenforschung for a Springer Theses Prize A breakthrough in the field of asymmetric epoxidation chemistry This work could lead to numerous commercial applications Includes supplementary material: sn.pub/extras
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