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Magnetic Isotope Effect in Radical Reactions : An Introduction - Taschenbuch

1996, ISBN: 3211827846

[EAN: 9783211827840], Neubuch, [SC: 0.0], [PU: Springer Vienna], MAGNET (PHYSIKALISCH) - MAGNETISMUS; CHEMICALREACTION; CHEMISTRY; GEOCHEMISTRY; KETONES; KINETICS; POLYMER, Druck auf Anfr… Mehr…

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Kev M. Salikhov:

Magnetic Isotope Effect in Radical Reactions - Taschenbuch

1996, ISBN: 3211827846

[EAN: 9783211827840], Neubuch, [PU: Springer Vienna], MAGNET (PHYSIKALISCH) - MAGNETISMUS CHEMICALREACTION CHEMISTRY GEOCHEMISTRY KETONES KINETICS POLYMER CHEMIE THEORETISCHE CHEMICAL REA… Mehr…

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Salikhov, Kev M.:
Magnetic Isotope Effect in Radical Reactions: An Introduction - Taschenbuch

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ISBN: 9783211827840

Springer, Taschenbuch, Auflage: Softcover reprint of the original 1st ed. 1996, 160 Seiten, Publiziert: 2013-10-04T00:00:01Z, Produktgruppe: Buch, Hersteller-Nr.: 2 black & white illustra… Mehr…

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K. M. Salikhov:
Magnetic Isotope Effect in Radical Reactions: An Introduction - Taschenbuch

ISBN: 9783211827840

Paperback / softback. New. This book presents the physical background (both theoretical and experimental) of the magnetic isotope effects in radical reactions in solutions.This book will… Mehr…

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Salikhov, Kev M.:
Magnetic Isotope Effect in Radical Reactions: An Introduction - Taschenbuch

ISBN: 9783211827840

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Details zum Buch
Magnetic Isotope Effect in Radical Reactions: An Introduction
Autor:
Titel:
ISBN-Nummer:

3211827846


In the last two decades it was demonstrated that, in addition to masses and charges, magnetic moments of nuclei are able to influence remarkably chemical reactions. This book presents the physical background (both theoretical and experimental) of the magnetic isotope effects in radical reactions in solutions. Special attention has been paid to the quantitative interpretation of the available experimental data. This book will be useful for physicists, chemists and biologists employing the isotope effect in their investigations as well as for those involved in isotope separation and isotope enrichment projects. Additionally, the magnetic isotope effect appears to be important in geochemistry and cosmochemistry. The book can be recommended for postgraduates and senior undergraduate students.

Detailangaben zum Buch - Magnetic Isotope Effect in Radical Reactions: An Introduction


EAN (ISBN-13): 9783211827840
ISBN (ISBN-10): 3211827846
Taschenbuch
Erscheinungsjahr: 1996
Herausgeber: Springer

Buch in der Datenbank seit 2012-02-03T03:09:28+01:00 (Berlin)
Detailseite zuletzt geändert am 2023-07-28T16:44:30+02:00 (Berlin)
ISBN/EAN: 3211827846

ISBN - alternative Schreibweisen:
3-211-82784-6, 978-3-211-82784-0
Alternative Schreibweisen und verwandte Suchbegriffe:
Titel des Buches: the magnetic effect, isotope, constantin, constantine, radical reactions

Daten vom Verlag:

Autor/in: Kev M. Salikhov
Titel: Magnetic Isotope Effect in Radical Reactions - An Introduction
Verlag: Springer; Springer Wien
147 Seiten
Erscheinungsjahr: 1996-08-02
Vienna; AT
Gewicht: 0,454 kg
Sprache: Englisch
53,49 € (DE)
54,99 € (AT)
59,00 CHF (CH)
POD
VIII, 147 p. 2 illus.

BC; Theoretical and Computational Chemistry; Hardcover, Softcover / Chemie/Theoretische Chemie; Quanten- und theoretische Chemie; Verstehen; chemical reaction; chemistry; geochemistry; isotope; ketones; kinetics; polymer; Physical Chemistry; Organic Chemistry; Food Science; Mineralogy; Theoretical Chemistry; Physical Chemistry; Organic Chemistry; Food Science; Mineralogy; Physikalische Chemie; Organische Chemie; Lebensmittel- und Getränketechnologie; Petrologie (Gesteinskunde), Petrografie und Mineralogie; EA

1 Introduction.- 1.1 Origin of magnetic isotope effect in radical reactions.- 1.2 Favourable conditions for magnetic isotope effect.- 1.3 Some specific features of magnetic isotope effect.- 1.4 What can be gained from magnetic isotope effect?.- 1.5 Basic steps in studying magnetic isotope effect.- 2 Main concepts of the theory of magnetic isotope effect.- 2.1 Macroscopic and microscopic parameters.- 2.2 Radical pairs.- 2.3 Multiplicity and reactivity of radical pairs.- 2.4 The hyperfine coupling.- 2.5 Singlet-triplet transitions in radical pairs induced by the hyperfine interaction.- 2.6 Manifestations of radical pair spin conservation rules in singlet-triplet mixing induced by the isotropic hyperfine coupling.- 2.7 Kinetic equations for radical pair recombination.- 3 Theoretical description of magnetic isotope effect in the Earth’s magnetic field.- 3.1 Radical pairs with one magnetic nucleus (isotropic hyperfine coupling).- 3.2 Radical pairs with magnetically equivalent nuclei (isotropic hyperfine coupling).- 3.3 Radical pairs with many magnetically non-equivalent nuclei (isotropic hyperfine coupling).- 3.4 Magnetic isotope effect induced by the anisotropic hyperfine interaction (paramagnetic relaxation).- 3.5 Magnetic isotope effect in reaction kinetics.- 4 Magnetic isotope effect in the presence of external magnetic fields.- 4.1 Magnetic isotope effect as affected by constant fields.- 4.1.1 Anisotropic hyperfine interaction (the so-called relaxation mechanism of singlet-triplet transitions).- 4.1.2 Isotropic hyperfine interaction.- 4.2 Resonant microwave field pumping.- 5 Experimental evidences of magnetic isotope effect.- 5.1 Enrichment of 13C in dibenzyl ketone during photolysis.- 5.1.1 Photolysis of dibenzyl ketone in homogeneous solutions.- 5.1.2 Photolysis of dibenzyl ketone in micelles.- 5.1.3 Magnetic isotope effect in photoinduced emulsion polymerization.- 5.2 Magnetic isotope effect in radiolysis of aromatic hydrocarbon solutions in alkanes.- 5.3 Magnetic isotope effect for heavy elements.- 5.4 Magnetic isotope effect for biradical reaction pathways.- 5.5 Magnetic isotope effect in reaction rates.- 5.6 Isotope enrichment by resonant microwave pumping.- 6 Some perspectives.- References.

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