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ISBN: 9780792335221

The analogy between the chemistry of molecular transition metal clusters and the processes of chemisorption and catalysis at metal surfaces (the Cluster Surface analogy) has for a number … Mehr…

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1995

ISBN: 9780792335221

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Editor: Farrugia, L.J. Springer, Hardcover, Auflage: 1, 376 Seiten, Publiziert: 1995-05-31T00:00:01Z, Produktgruppe: Book, 0.71 kg, Inorganic, Chemistry, Science & Math, Subjects, Books, … Mehr…

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The Synergy Between Dynamics and Reactivity at Clusters and Surfaces L.J. Farrugia Editor
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9780792335221


The analogy between the chemistry of molecular transition metal clusters and the processes of chemisorption and catalysis at metal surfaces (the Cluster Surface analogy) has for a number of years provided an interplay between experimental and theoretical inorganic and physical chemists. This collaborative approach has born fruit in the use of well defined modes of metal-ligand bonding in discrete molecular clusters, models for metal-ligand binding on surfaces. Some of the key topics discussed in The Synergy between Dynamics and Reactivity at Clusters and Surfaces are: (1) Mechanisms of the fluxional behaviour in clusters in the liquid phase and the connections with diffusion processes on extended surfaces. The role of metal-metal bond breaking in diffusion. (2) Analogies in the structure of chemisorbed species and related ligands on metallic clusters. (3) Analogies between benzene surface chemistry on extended metal surfaces and on metal surfaces in molecular cluster compounds with particular reference to structural distortions. (4) The role of mobile precursors for dissociation of chemisorption on extended metals and on clusters. Are there analogies in the ligand attachment during cluster compound synthesis? (5) The role of defect sites on metal surfaces in catalyzing chemical reactions and the connection to the special bonding properties of sites on metal clusters having lowest metal-metal coordination. (6) The size of metal clusters needed to mimic surface phenomena on bulk metal surfaces. Different sites needed for different phenomena.

Detailangaben zum Buch - The Synergy Between Dynamics and Reactivity at Clusters and Surfaces L.J. Farrugia Editor


EAN (ISBN-13): 9780792335221
ISBN (ISBN-10): 0792335228
Gebundene Ausgabe
Taschenbuch
Erscheinungsjahr: 1994
Herausgeber: Springer-Verlag New York, LLC Core >2

Buch in der Datenbank seit 2007-11-21T20:08:59+01:00 (Berlin)
Detailseite zuletzt geändert am 2024-02-29T02:41:17+01:00 (Berlin)
ISBN/EAN: 9780792335221

ISBN - alternative Schreibweisen:
0-7923-3522-8, 978-0-7923-3522-1
Alternative Schreibweisen und verwandte Suchbegriffe:
Titel des Buches: drym, dynamics surfaces proceedings

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