2014, ISBN: 9783642435331

Kartoniert, 276 Seiten, 235mm x 155mm x 16mm, Sprache(n): eng Nominated by the Max-Planck-Institut für Kohlenforschung for a Springer Theses Prize A breakthrough in the field of asymmetr… Mehr…

Kartoniert, 276 Seiten, 235mm x 155mm x 16mm, Sprache(n): eng Nominated by the Max-Planck-Institut für Kohlenforschung for a Springer Theses Prize A breakthrough in the field of asymmetric epoxidation chemistry This work could lead to numerous commercial applications Includes supplementary material: sn.pub/extrasCorinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic ¿, ¿-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She describes the unprecedented and powerful catalytic asymmetric hydro­peroxi­dation of ¿, ¿-enones, a process which produces optically active five-membered cyclic peroxyhemiketals in a single operation. She also proves the versatility and synthetic value of the cyclic peroxyhemiketals by converting them into highly enantioenriched acyclic and cyclic aldol products. Currently, these cyclic aldol products are inaccessible by any other synthetic means. Furthermore, cyclic peroxyhemiketals are precursors to optically active 1, 2-dioxolanes which are of biological relevance. This work is a breakthrough in the field of asymmetric epoxidation chemistry and outlines the most efficient method in the literature for generating highly enantioselective cyclic epoxyketones known to date. Versandkostenfreie Lieferung Asymmetriccounteranion-directedcatalysis, Asymmetricperoxidationreactions, Asymmetricsynthesisofepoxyketones, Cinchonaalkaloidderivativesasorganocatalysts, Organocatalyticepoxidationofunsaturatedketones, [PU: Springer, Berlin/Heidelberg/New York, NY]<

2014, ISBN: 3642435335

[EAN: 9783642435331], Neubuch, [PU: Springer Berlin Heidelberg], ASYMMETRICCOUNTERANION-DIRECTEDCATALYSIS; ASYMMETRICPEROXIDATIONREACTIONS; ASYMMETRICSYNTHESISOFEPOXYKETONES; CINCHONAALKA… Mehr…

[EAN: 9783642435331], Neubuch, [PU: Springer Berlin Heidelberg], ASYMMETRICCOUNTERANION-DIRECTEDCATALYSIS; ASYMMETRICPEROXIDATIONREACTIONS; ASYMMETRICSYNTHESISOFEPOXYKETONES; CINCHONAALKALOIDDERIVATIVESASORGANOCATALYSTS; ORGANOCATALYTICEPOXIDATIONOFUNSATURATEDKETONES, Druck auf Anfrage Neuware - Printed after ordering - Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic ,beta-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She describes the unprecedented and powerful catalytic asymmetric hydroperoxidation of ,beta-enones, a process which produces optically active five-membered cyclic peroxyhemiketals in a single operation. She also proves the versatility and synthetic value of the cyclic peroxyhemiketals by converting them into highly enantioenriched acyclic and cyclic aldol products. Currently, these cyclic aldol products are inaccessible by any other synthetic means. Furthermore, cyclic peroxyhemiketals are precursors to optically active 1,2-dioxolanes which are of biological relevance. This work is a breakthrough in the field of asymmetric epoxidation chemistry and outlines the most efficient method in the literature for generating highly enantioselective cyclic epoxyketones known to date. 276 pp. Englisch, Books<

2014, ISBN: 3642435335

[EAN: 9783642435331], Neubuch, [SC: 0.0], [PU: Springer Berlin Heidelberg], ASYMMETRICCOUNTERANION-DIRECTEDCATALYSIS; ASYMMETRICPEROXIDATIONREACTIONS; ASYMMETRICSYNTHESISOFEPOXYKETONES; C… Mehr…

[EAN: 9783642435331], Neubuch, [SC: 0.0], [PU: Springer Berlin Heidelberg], ASYMMETRICCOUNTERANION-DIRECTEDCATALYSIS; ASYMMETRICPEROXIDATIONREACTIONS; ASYMMETRICSYNTHESISOFEPOXYKETONES; CINCHONAALKALOIDDERIVATIVESASORGANOCATALYSTS; ORGANOCATALYTICEPOXIDATIONOFUNSATURATEDKETONES, Druck auf Anfrage Neuware - Printed after ordering - Corinna Reisinger has developed a new organocatalytic asymmetric epoxidation of cyclic and acyclic ,beta-unsaturated ketones. In this thesis, Corinna documents her methodology, using primary amine salts as catalysts, and hydrogen peroxide as an inexpensive and environmentally benign oxidant. She describes the unprecedented and powerful catalytic asymmetric hydroperoxidation of ,beta-enones, a process which produces optically active five-membered cyclic peroxyhemiketals in a single operation. She also proves the versatility and synthetic value of the cyclic peroxyhemiketals by converting them into highly enantioenriched acyclic and cyclic aldol products. Currently, these cyclic aldol products are inaccessible by any other synthetic means. Furthermore, cyclic peroxyhemiketals are precursors to optically active 1,2-dioxolanes which are of biological relevance. This work is a breakthrough in the field of asymmetric epoxidation chemistry and outlines the most efficient method in the literature for generating highly enantioselective cyclic epoxyketones known to date., Books<

2012, ISBN: 9783642435331

*Epoxidations and Hydroperoxidations of -Unsaturated Ketones* - An Approach through Asymmetric Organocatalysis. Auflage 2012 / Taschenbuch für 106.99 € / Aus dem Bereich: Bücher, Wissensc… Mehr…

*Epoxidations and Hydroperoxidations of -Unsaturated Ketones* - An Approach through Asymmetric Organocatalysis. Auflage 2012 / Taschenbuch für 106.99 € / Aus dem Bereich: Bücher, Wissenschaft, Chemie Medien > Bücher nein Buch (kartoniert) Hardcover;Naturwissenschaften, Medizin, Informatik, Technik;Organische Chemie, Springer Berlin Heidelberg<